Work

A Film of Hydrophobic Cations Reshapes the Electric Double Layer at the Metal/Water Interface

Year: 2026

Type: article

Abstract: In recent studies, it was observed that the addition of large hydrophobic cations, such as tetrabutylammonium (TBA+), into aqueous electrolytes enhances the rate of the hydrogen evolution reaction. This opens a promising perspective for optimizing electrochemical reactions via tuning of the electrolyte composition. We have con- structed a THz ATR spectroelectrochemical cell that is able to unravel the underlying molecular details in the interfacial layer at the gold/water interface. We find spec- troscopic evidence for the formation of a TBA+ rich film. Accompanying molecular dynamics simulations quantify the balance of electrostatics and hydrophobic solvation driving forces that dictates the TBA+ film formation. The composition of the film is strongly voltage-dependent, as confirmed by simulations. At positive potentials above 0.6 V versus Ag/AgCl, TBA+ only partially desorbs, causing the formation of a coad- sorbed TBA+ and Cl− layer and the partial rehydration of the surface. By our joint experimental-theoretical study, we disclose that a film of hydrophobic TBA+ cations has a major impact on the structure of the hydrogen bond network at the electrode- water interface. This allows rationalizing at the molecular level the ions-induced struc- tural changes at the interface that tune the catalytic performances.

Source: Journal of the American Chemical Society

DOI: 10.1021/jacs.5c11586