Work

Identical-particle symmetry-enabled complete coherent control of ultracold atomic and molecular collisions

Year: 2026
Type: article
Abstract: We show that exchange symmetry in collisions of identical particles enables symmetry-protected coherent control of the total scattering cross section. For identical fermions, antisymmetrization enforces a common control phase among contributing channels within a given parity sector, yielding maximal control visibility. For identical bosons, phase-locking persists but with reduced visibility due to additional exchange (satellite) contributions. Collisions of distinguishable particles lack this symmetry-imposed phase-locking, leading to lower controllability and visibility. We elucidate these principles through coupled-channel quantum-scattering calculations for lithium-lithium collisions, comparing the $^{6}\mathrm{Li}{-}^{6}\mathrm{Li}$ (identical fermions), $^{7}\mathrm{Li}{-}^{7}\mathrm{Li}$ (identical bosons), and $^{6}\mathrm{Li}{-}^{7}\mathrm{Li}$ (distinguishable) systems. Furthermore, in the identical-particle cases, symmetry-enforced phase-locking enables full control over the parity of the final state even beyond the ultracold regime. This mechanism is broadly applicable to identical-particle collisions, including homonuclear molecules for which established approaches--DC electric fields or microwave shielding--are ineffective or unavailable.
Language: English
Open Access status: green
OpenAlex ID: W7213323908
FWCI:
Cites: 43
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Related to: 10