Novel Cu-Fe codoped NiO nanocrystalline semiconductors with superior room-temperature ferromagnetism and high dielectric performance for spintronic devices
Year: 2025
Type: article
Abstract: Nickel oxide (NiO) has the potential to be a p-type diluted magnetic semiconductor, but its limited room-temperature ferromagnetism (RTFM) and dielectric properties make it less useful. This study addresses these limitations by synthesizing pure NiO, Cu-doped NiO (Ni 0.95 Cu 0.05 O), and Cu-Fe codoped NiO (Ni 0.95 Cu 0.025 Fe 0.025 O) nanopowders using NaOH-assisted co-precipitation. Rietveld-refined X-ray diffraction (XRD) confirmed a cubic structure with lattice parameter changes, while scanning electron microscopy/transmission electron microscopy (SEM/TEM) revealed reduced crystallite sizes from 23 to 10 nm. X-ray photoelectron spectroscopy (XPS) confirmed Cu 2+ and Fe 3+ oxidation states and oxygen vacancies. The measurements showed that the codoped sample exhibited a colossal dielectric constant (ε′ >10 5 at 50 Hz) and enhanced saturation magnetization (3.5 emu/g vs. 0.47 emu/g for pure NiO). These improvements arise from synergistic effects: Cu doping promotes oxygen vacancies for space-charge polarization, while Fe enables bound magnetic polarons (BMPs). Thus, Cu-Fe codoped NiO emerges as a prime candidate for spintronics and high-density energy storage applications.
Institutions: Qassim University, Imam Abdulrahman Bin Faisal University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $1,600
OpenAlex ID: W4417311846